Publications

 

Peer-Reviewed Publications

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58.      M. Sellin, S. M. Rupf, P. A. Albrecht, R. M. Gomila, A. Frontera, M. Malischewski*, „Binding Four Iodine Atoms to a Single Pnictogen Atom in Halogen-Bonded Assemblies of Nitroprusside [Fe(CN)5NO]2– and C2I2”,Cryst. Growth. Des. accepted

57.       L. Arya, S. M. Rupf, Y. Shandilya, J. Spandl, M. Malischewski, O. Nachtigall*, „Charge Distribution in Mixed-Valent Lindqvist-Type Vanadium Alkoxides”, Chem. Eur. J. accepted.

56.     I. Suzana*, A. Mikhailov, E. Moreno-Pineda, J. Forté, S. Pillet, E.-E. Bendeif, C. Lecourt, W. Wernsdorfer, M. Malischewski*, V. Marvaud*, „Photo-switching of Magnetic Behaviour in Multifunctional Hetero-tetrametallic Complexes”, submitted.

55.      A. L. Moshtaha, T.-N. Streit, J. Parche, R. Sievers, M. Malischewski*, „Expanding Cyanide-Bridged Weakly Coordinating Anions through the Brominated Silver Salt Ag[BCNBBr]“, Chem. Eur. J. 2026, (Early View), e71310. https://doi.org/10.1002/chem.71310

54.       A. Keimer, J. Rettig, T.-N. Streit, B. Barthel, M. Calmels, M. Malischewski, F.-L. Haut*, „Sulfur-Directed Construction of Vinyl Cyclopropanes from 1,3‑Dienes“, Angew. Chem. Int. Ed. 2026, 65, e4468205. https://doi.org/10.1002/anie.4468205

53.     J. Parche, R. Sievers, T.-N. Streit, M. Malischewski*, „Accessing Osmium(VI) Nitrido Complexes with N-Heterocyclic Carbene Ligands“, Dalton Trans. 2026, 55, 5161-5167. https://doi.org/10.1039/D6DT00234J

52.      T.-N. Streit, M. Sellin*, B. Lazarevski, O. S. Wenger*, M. Malischewski*, „Controlling Redox and Photophysical Properties of First-Row Transition Metal Complexes via Ligand Perhalogenation“, Inorg. Chem. 2026, 65, 5374-5386.  https://doi.org/10.1021/acs.inorgchem.5c05333

51.       T.-N. Streit, M. Sellin, S. M. Rupf, R. M. Gomila, A. Frontera*, M. Malischewski*, „4-fold Protonation of Tetracyanometalates in Superacids: Hydrogen and π-Hole Bonding in the Solid State“, Inorg. Chem. 2026, 65, 892-901. https://doi.org/10.1021/acs.inorgchem.5c05224

50.       W. R. Berg, A. L. Moshtaha, R. Sievers, M. Reimann, T.-N. Streit, S. M. Rupf, M. Kaupp, M. Malischewski*, „A facile route to ‘naked’ Ag+ ions enabling the coordination of the weak Lewis base Ni(CO)4“, Chem. Sci. 2026, 17, 406-411. https://doi.org/10.1039/D5SC05589J

49.       I. Suzana, S. M. Rupf, C. Pécou, E. Rousset, A. K. Fazlur Rahman, B. Klemke,  V. Marvaud*, M. Malischewski*, “Chemical and Magnetic Tuneability in Structurally Defined Heterotrimetallic Dendrimers”, Inorg. Chem. Front. 2026, 13, 1821-1828.  https://doi.org/10.1039/D5QI02242H

48.      N. G. Kub, R.Sievers, M. Reimann, T.-N. Streit, S. Steinhauer, J. Schlögl, M. Kaupp, M. Malischewski*, „Coexistence of Metallocene Cations and Anions“, J. Am. Chem. Soc. 2025, 147, 34641–34646. https://doi.org/10.1021/jacs.5c09718

47.      A. Moshtaha, E. M. Peter, R. Sievers, T.-N. Streit, M. Malischewski*, „Synthesis of the Soft Lewis Superacid Tris(4-bromo-2,3,5,6-tetrafluorophenyl)borane B(C6F4Br)3 via C‒Ag to C‒B Transmetalation“, Chem. Eur. J. 2025, 31, e02240.  https://doi.org/10.1002/chem.202502240

46.      J. Parche, R. Sievers, T.-N. Streit, M. Malischewski*, „Osmium(VI) Nitrido Complexes with Perfluorinated Alcoholate Ligands: Expanding Ligand Scope through a Simple Silver Oxide-Mediated Synthesis Route“, Eur. J. Inorg. Chem. 2025, 28, e2500335, https://doi.org/10.1002/ejic.202500335   

45.      M. Sellin, S. M. Rupf, M. Malischewski*, „Synthesis, crystal structure and Hirshfeld surface analysis of the two-dimensional hydrogen-bonded network [TCNQ-H2]2+[AsF6]2−“, Acta Cryst. 2025, E81, 840-843.  https://doi.org/10.1107/S2056989025007108

44.       R. Sievers, N. Hartmann, P. S. Riemann, T.-N. Streit, M. Malischewski*, „Stimulus-responsive metallocenes: a photo/thermal switch enabled by the perfluorinated Cp* ligand“, Chem. Sci., 2025, 16, 11949-11953.  https://doi.org/10.1039/D5SC02784E

43.       R. Sievers, N. G. Kub, T.-N. Streit, M. Reimann, G. Thiele, M. Kaupp, M. Malischewski*, „Unlocking a Ferrocenium Superoxidizer with the Perfluorinated Cp* Ligand“, Angew. Chem. Int. Ed. 2025, 64, e202505783. e202505783.

42.       T.-N. Streit, R. Sievers, M. Sellin*, M. Malischewski*, „Revisiting C6F5NC: The quest for isocyanide ligands with strong π-acceptor properties evaluated by energy decomposition analysis“, ACS Omega 2025, 10, 35095–35102. https://doi.org/10.1021/acsomega.5c04766

41.       R. Sievers, N. G. Kub, T.-N. Streit, S. M. Rupf, M. Malischewski*, „Coexistence of the Perfluorinated Cp* Anion with Oxidizing and Electrophilic Cations“, Chem. Eur. J. 2025, 31, e202500743. https://doi.org/10.1002/chem.202500743

40.     I. Suzana*, J. Forté, S. Pillet, E.-E. Bendeif, M. Malischewski*, V. Marvaud*, „Unlocking New Frontiers: Photo-Isomerism and Magnetic Properties in Multifunctional Hetero-Tetra-Metallic Complexes“, Chem. Eur. J. 2025, 31, e202402601. https://doi.org/10.1002/chem.202402601

39.       W. R. Berg, M. Reimann, R. Sievers, S. M. Rupf, J. Schlögl, K. Weisser, K. B. Krause, C. Limberg, M. Kaupp, M. Malischewski*, „Solvent-dependent Reactivity of Fe(CO)5 Under Superacidic and Oxidative Conditions“, J. Am. Chem. Soc. 2025, 147, 3039–3046. https://doi.org/10.1021/jacs.4c09595

38.      L. P. Griffin, R. Sievers, S. Aldridge, R. M. Gomila, A. Frontera*, M. Malischewski*, „Crystallographic Evidence for Bi(I) as the heaviest halogen bond acceptor“, J. Am. Chem. Soc. 2024, 146, 29877-29882. https://doi.org/10.1021/jacs.4c11901

37.      T.-N. Streit, J. Langwald, R. Gomila, A. Frontera*, M. Malischewski*, „Structural diversity of supramolecular networks formed between polycyanometalates and sulfur-based chalcogen bond donors“, CrystEngComm, 2024, 26, 3627-3633. https://doi.org/10.1039/D4CE00454J

36.       N. G. Kub, R. Sievers, J. Parche, M. Malischewski*, „Substitution Lability of the Perfluorinated Cp* Ligand in [Rh(COD)(C5(CF3)5)] towards Triphenylpnictogens EPh3 (E = N, P, As, Sb, Bi)“, Chem. Eur. J. 2024, 30, e202400427. https://doi.org/10.1002/chem.202400427

35.       R. Sievers, M. Reimann, N. G. Kub, S. M. Rupf, M. Kaupp, M. Malischewski*, „Synthesis and Characterization of Stable Coinage Metal (Cu, Ag, Au) Cyclopentadienyl Complexes“, Chem. Sci., 2024, 15, 2990-2995. https://doi.org/10.1039/D3SC06299F

34.       T.-N. Streit, R. M. Gomila, R. Sievers, A. Frontera*, M. Malischewski*, „CF3-substitued sulfonium cations as efficient chalcogen bond donors towards cyanometalates“, CrystEngComm, 2024, 26, 594-598. https://doi.org/10.1039/D3CE01155K

33.       M. Keilwerth, W. Mao, M. Malischewski, S. Jannuzzi, K. Breitwieser, F. Heinemann, A. Scheurer, S. DeBeer*, E. Bill, D. Munz*, K. Meyer*, „The synthesis and characterization of an iron(VII) nitrido complex“, Nature Chem. 2024, 16, 514-520. https://doi.org/10.1038/s41557-023-01418-4

32.       Y. Schulte, C. Wölper, S. M. Rupf, M. Malischewski, D. J. SantaLucia, F. Neese,  G. Haberhauer*, S. Schulz*, „Structural Characterization and Reactivity of a Room Temperature-Stable, Antiaromatic Cyclopentadienyl Cation Salt”, Nature Chem. 2024, 16, 651-657. https://doi.org/10.1038/s41557-023-01417-5

31.      S. M. Rupf, S. Pan, A. Moshtaha, G. Frenking*, M. Malischewski*, „Structural Characterization and Bonding Analysis of [Hg{Fe(CO)5}2]2+ [SbF6]-2”, J. Am. Chem. Soc. 2023, 145, 15353-15359. https://doi.org/10.1021/jacs.3c03064

30.       A. E. Mansour, R. Warren, D. Lungwitz, M. Forster, U. Scherf, A. Opitz, M. Malischewski, N. Koch*, „Coordination of tetracyanoquinodimethane-derivatives with tris(pentafluorophenyl)borane provides stronger p-dopants with enhanced stability“, ACS Appl. Mater. Interfaces 2023, 15, 46148–46156. https://doi.org/10.1021/acsami.3c10373

29.       S. M. Rupf, R. Sievers, P. S. Riemann, M. Reimann, M. Kaupp, C. Fasting, M. Malischewski*, „Persilylation of ferrocene: the ultimate discipline in sterically overcrowded metal complexes”, Dalton Trans. 2023, 52, 6870-6875. https://doi.org/10.1039/D3DT01133J 

28.       J. Parche, S. M. Rupf, R. Sievers, M. Malischewski*, „Substitution lability of the perfluorinated Cp* ligand in Rh(I) complexes”, Dalton Trans. 2023, 52, 5496-5502. https://doi.org/10.1039/D3DT00425B

27.     R. Sievers, J. Parche, N. G. Kub, M. Malischewski*, „Synthesis and Coordination   Chemistry of Fluorinated Cyclopentadienyl Ligands”, Synlett, 2023, 34, 1079-1086.  https://doi.org/10.1055/s-0042-1751426

26.       S. M. Rupf, A. L. Moshtaha, M. Malischewski*, „A Decacationic Ferrocen-Based Metallostar”, Chem. Sci. 2023, 14, 1132-1137. https://doi.org/10.1002/anie.20221114747

25.     R. Sievers, M. Sellin, S. M. Rupf, M. Malischewski*, „Introducing the Perfluorinated Cp* Ligand into Coordination Chemistry”, Angew. Chem. Int. Ed. 2022, 61, e202211147. https://doi.org/10.1002/anie.202211147

24.    S. M. Rupf, I. S. Dimitrova, G. Schröder, M. Malischewski*, „Preparation and One-Electron Oxidation of Decabromoferrocene”, Organometallics, 2022, 41, 1261-1267. https://doi.org/10.1021/acs.organomet.2c00157

23.     K. F. Hoffmann, D. Battke, P. Golz, S. M. Rupf, M. Malischewski, S. Riedel*, „Structural Proof of the Tris(pentafluorophenyl)methylium Cation”, Angew. Chem. Int. Ed. 2022, e202203777. https://doi.org/10.1002/anie.202203777

22.     P. A. Albrecht, S. M. Rupf, M. Sellin, J. Schlögl, S. Riedel, M. Malischewski*, „Increasing the oxidation power of TCNQ by coordination of B(C6F5)3", Chem. Commun. 2022, 58, 4958-4961. https://doi.org/10.1039/D2CC00314G

21.      M. Gaedke, H. Hupatz, F. Witte, S. M. Rupf, C. Douglas, H. V. Schröder, L. Fischer, M. Malischewski, B. Paulus, C. A. Schalley*, „Sequence-sorted redox-switchable hetero[3]rotaxanes“, Org. Chem. Front., 2022, 9, 64-74. https://doi.org/10.1039/D1QO01553B

20.      M. Sellin, S. M. Rupf, M. Malischewski*, „Cubic Three-Dimensional Networks of the Cyanometalate [Fe(CN)6]3– with the Ditopic Halogen Bond Donor Diiodoacetylene C2I2”, Cryst. Growth Des. 2021, 21, 5515–5520. https://doi.org/10.1021/acs.cgd.1c00882

19.     M. Sellin, S. M. Rupf, U. Abram, M. Malischewski*, „Eightfold Electrophilic Methylation of Octacyanotungstate [W(CN)8]4–/3–: Preparation of Homoleptic, Eight-Coordinate Methyl Isocyanide Complexes [W(CNMe)8]4+/5+”, Inorg. Chem. 2021, 60, 5917–5924. https://doi.org/10.1021/acs.inorgchem.1c00326

18.      S. M. Rupf, G. Schröder, R. Sievers, M. Malischewski*, „Tenfold Metalation of Ferrocene: Synthesis, Structures and Metallophilic Interactions in FeC10(HgX)10“, Chem. Eur. J., 2021, 27, 5125-5129. https://doi.org/10.1002/chem.202100261

17.      P. Voßnacker, T. Keilhack, N. Schwarze, K. Sonnenberg, K. Seppelt, M. Malischewski*, S. Riedel*, „From Missing Links to New Records: A Series of Novel Polychlorine Anions“, Eur. J. Inorg. Chem. 2021, 2021, 1034-1040. https://doi.org/10.1002/ejic.202001072

16.       M. Sellin, S. M. Rupf, Y. Zhang, M. Malischewski*, „Bi- and Trifurcated Halogen Bonding M–C≡N···I in 1D, 2D, and 3D Supramolecular Network Structures of Co-Crystallized Diiodoacetylene C2I2 and Tetracyanonickelate [Ni(CN)4]2–“, Cryst. Growth. Des. 2020, 20, 7104-7110. https://doi.org/10.1021/acs.cgd.0c01208

15.      S. M. Rupf, P. Pröhm, M. Malischewski*, „The [2+2] cycloaddition product of perhalogenated cyclopentadienyl cations: structural characterization of salts of the [C10Cl10]2+ and [C10Br10]2+ dications“, Chem. Commun. 2020, 56, 9834-9837. https://doi.org/10.1039/D0CC04226A

14.      M. Sellin, V. Marvaud, M. Malischewski*, „Isolation and Structural Characterization of Eightfold Protonated Octacyanometalates [M(CNH)8]4+ (M=MoIV, WIV) from Superacids”, Angew. Chem. Int. Ed. 2020, 59, 10519-10522.  https://doi.org/10.1002/anie.202002366

13.       M. Sellin, M. Malischewski*, „Crystal structure of [K(18-crown-6)]+2[Pt(CN)4]2−“, Acta Cryst. 2019, E75, 1871-1874. https://doi.org/10.1107/S2056989019015238

12.      M. Malischewski*, K. Seppelt, „Structural characterization of potassium salts of the decamethylmanganocene anion Cp*2Mn-“, Dalton Trans. 2019, 48, 17078-17082. https://doi.org/10.1039/C9DT03551F

11.      M. Malischewski*, K. Seppelt, J. Sutter, D. Munz, K. Meyer*, „A Ferrocene-Based Dicationic Iron(IV) Carbonyl Complex“, Angew. Chem. Int. Ed. 2018, 57, 14597-14601. https://doi.org/10.1002/anie.201809464

10.      M. Malischewski, E. V. Bukovsky, S. H. Strauss*, K. Seppelt, „Structure of (SiEt3)2(B12F12). Another example of R3SiFE bridge bonding (EB, Al, Si)“, J. Fluor. Chem. 2018, 212, 107-111. https://doi.org/10.1016/j.jfluchem.2018.04.010

 9.     M. Malischewski*, K. Seppelt, „Isolation and Characterization of a Non-Rigid Hexamethylbenzene-SO2+ Complex“, Angew. Chem. Int. Ed. 2017, 56, 16495-16497. https://doi.org/10.1002/anie.201708552

 8.      M. Malischewski*, K. Seppelt, J. Sutter, F. W. Heinemann, B. Dittrich, K. Meyer*, „Protonation of Ferrocene: A Low-Temperature X-ray Diffraction Study of [Cp2FeH] (PF6) Reveals an Iron-Bound Hydrido Ligand“, Angew. Chem. Int. Ed. 2017, 56, 13372-13376. https://doi.org/10.1002/anie.201704854

 7.     M. Malischewski*, K. Seppelt, „Crystal Structure Determination of the Pentagonal-Pyramidal Hexamethylbenzene Dication C6(CH3)62+“, Angew. Chem. Int. Ed. 2017, 56, 368-370. https://doi.org/10.1002/anie.201608795           

 6.      M. Malischewski, D. V. Peryshkov, E. V. Bukovsky, K. Seppelt*, S. H. Strauss*, „Structures of M2(SO2)6B12F12 (M = Ag, K) and Ag2(H2O)4B12F12  - Comparison of the Coordination of SO2 versus H2O and of B12F122- versus Other Weakly Coordinating Anions to Metal Ions in the Solid State“, Inorg. Chem. 2016, 55, 12254-12262. https://doi.org/10.1021/acs.inorgchem.6b01980

 5.      M. Malischewski*, M. Adelhardt, J. Sutter, K. Meyer*, K. Seppelt, „Isolation and structural and electronic characterization of salts of the decamethylferrocene dication“, Science, 2016, 353, 678-682. https://doi.org/10.1126/science.aaf6362

 4.       M. Malischewski*, E. V. Bukovsky, S. H. Strauss, K. Seppelt, „Jahn–Teller Effect in the B12F12 Radical Anion and Energetic Preference of an Octahedral B6(BF2)6 Cluster Structure over an Icosahedral Structure for the Elusive Neutral B12F12“, Inorg. Chem. 2015, 54, 11563-11566. https://doi.org/10.1021/acs.inorgchem.5b02256

 3.       M. Malischewski*, K. Seppelt, „Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO3F)2”,  Acta Cryst. 2015, E71, 363-365. https://doi.org/10.1107/S2056989015004788

 2.      O. Mallow, M. A. Khanfar, M. Malischewski, P. Finke, M. Hesse, E. Lork, T. Augenstein, F. Breher, J. R. Harmer, N. V. Vasilieva, A. Zibarev, A. S. Bogomyakov, K. Seppelt, J. Beckmann*, „Diaryldichalcogenide radical cations“, Chem. Sci. 2015, 6, 497-504. https://doi.org/10.1039/C4SC02964J

 1.     H. Poleschner*, S. Ellrodt, M. Malischewski, J.-y. Nakatsuji, C.Rohner, K. Seppelt, „Trip2C6H3SeF: the first isolated selenenyl fluoride“, Angew. Chem. Int. Ed. 2012, 51, 419-422. https://doi.org/10.1002/anie.201106708

 

Book Chapters

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2.        M. Malischewski, „Very High Oxidation States in Organometallic Chemistry” in Comprehensive Organometallic Chemistry IV: Volume 1 (Parkin, G., Meyer, K., O'Hare, D. (eds.)), Elsevier, 2022, 109-134. https://doi.org/10.1016/b978-0-12-820206-7.00004-4

1.     M. Malischewski, K. Seppelt, „Oxidation reactions on benzenes and ferrocenes“ in „The Curious World of Fluorinated Molecules“, Elsevier, 2020, 409-423. https://doi.org/10.1016/B978-0-12-819874-2.00015-1

 

Other Articles

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2.         M. Malischewski, „Blickpunkt Nachwuchs: Supersäuren und starke Oxidationsmittel“, Nachr. Chem. 2024, 72 (7), 70-71. https://doi.org/10.1002/nadc.20244143188

1.         M. Malischewski, „19. Deutscher Fluortag in Schmitten“, Nachr. Chem. 2022, 70, 80. https://doi.org/10.1002/nadc.20224132434